Origin of the exotic blue color of copper-containing historical pigments.

@article{GarcaFernndez2015OriginOT,
  title={Origin of the exotic blue color of copper-containing historical pigments.},
  author={P. Garc{\'i}a-Fern{\'a}ndez and M. Moreno and J. A. Aramburu},
  journal={Inorganic chemistry},
  year={2015},
  volume={54 1},
  pages={
          192-9
        }
}
The study of chemical factors that influence pigment coloring is a field of fundamental interest that is still dominated by many uncertainties. In this Article, we investigate, by means of ab initio calculations, the origin of the unusual bright blue color displayed by historical Egyptian Blue (CaCuSi4O10) and Han Blue (BaCuSi4O10) pigments that is surprisingly not found in other compounds like BaCuSi2O6 or CaCuO2 containing the same CuO4(6-) chromophore. We show that the differences in hue… Expand
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