Orientation selection in high-field RIDME and PELDOR experiments involving low-spin CoII ions.

@article{Giannoulis2018OrientationSI,
  title={Orientation selection in high-field RIDME and PELDOR experiments involving low-spin CoII ions.},
  author={A. Giannoulis and Claire L Motion and Maria Oranges and M. B{\"u}hl and Graham M. Smith and B. Bode},
  journal={Physical chemistry chemical physics : PCCP},
  year={2018},
  volume={20 4},
  pages={
          2151-2154
        }
}
Orientation selective (OS) RIDME and PELDOR were conducted on a low-spin CoII complex coordinated by two nitroxide (NO) labelled 2,2':6',2''-terpyridine ligands. Co-NO RIDME at W- and Q-band gave insight into the relative orientation between the Co-NO interspin vector (rCo-NO) and the NO moiety. This was further supported by W-band Co-NO PELDOR that also allowed elucidating the relative orientation of the CoII and NO g-tensors. Differences to earlier predictions were confirmed by DFT… Expand
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