Orientation and stereodynamic paths of planar monodentate ligands in square planar nickel N2S complexes.

@article{Jenkins2010OrientationAS,
  title={Orientation and stereodynamic paths of planar monodentate ligands in square planar nickel N2S complexes.},
  author={Roxanne Michelle Jenkins and Michael Lee Singleton and Lauren Anne Leamer and Joseph H. Reibenspies and Marcetta Y. Darensbourg},
  journal={Inorganic chemistry},
  year={2010},
  volume={49 12},
  pages={
          5503-14
        }
}
The well-established presence of histidine donors in binding sites of Ni-containing biomolecules prompts the study of orientational preference and stereodynamic nature of flat monodentate ligands (L = imidazoles, pyridine and an N-heterocyclic carbene) bound to planar N(2)SNi moieties. Square planar [N(2)SNiL](n+) complexes are accessed through bridge-splitting reactions of dimeric, thiolate-S bridged [N(2)SNi](2) complexes. The solid state molecular structures of three mononuclear products… CONTINUE READING
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