Organophosphonate-Functionalized Lanthanopolyoxomolybdate: Synthesis, Characterization, Magnetism, Luminescence, and Catalysis of H2O2-Based Thioether Oxidation.

@article{Wang2018OrganophosphonateFunctionalizedLS,
  title={Organophosphonate-Functionalized Lanthanopolyoxomolybdate: Synthesis, Characterization, Magnetism, Luminescence, and Catalysis of H2O2-Based Thioether Oxidation.},
  author={Jiawei Wang and Yanjun Niu and Meng Zhang and Pengtao Ma and Chao Zhang and Jingyang Niu and Jingping Wang},
  journal={Inorganic chemistry},
  year={2018},
  volume={57 4},
  pages={1796-1805}
}
A novel class of organophosphonate-based polyoxomolybdate derivatives, K4H5[Ln3(H2O)14{(Mo8O24)(O3PCH2COO)3}2]·23H2O (Ln = Gd (1Gd), Tb (2Tb), Dy (3Dy)), have been fully investigated by a few characterization methods such as single-crystal X-ray crystallography, XRPD, elemental analysis, TGA, and IR spectra. The magnetic properties of 1Gd, 2Tb, and 3Dy were… CONTINUE READING