Organometallic derivatives of N,N′-ethylene bis(acetylacetoneiminato)vanadium(III) containing a vanadium–carbon σ-bond

@inproceedings{Gambarotta1985OrganometallicDO,
  title={Organometallic derivatives of N,N′-ethylene bis(acetylacetoneiminato)vanadium(III) containing a vanadium–carbon σ-bond},
  author={Sandro Gambarotta and Marinella Mazzanti and Carlo Floriani and Angiola Chiesi-Villa and Carlo Guastini},
  year={1985}
}
  • Sandro Gambarotta, Marinella Mazzanti, +2 authors Carlo Guastini
  • Published 1985
  • Chemistry
  • The alkylation of N,N′-ethylenebis(acetylacetoneiminato)chlorovanadium(III)tetrahydrofuran, [Cl-V(acacen)(thf)]using Grignard reagents gave the corresponding organometallic derivatives [R-V(acacen)]2[R = Me, Ph, PhCH2] having a dimeric Structure, via the sharing of one of the oxygens from the Schiff base, and containing a V-C σ-bond [2.156(7)A= PhCH2]. 

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