Organocopper(III) Spiro Complexes: Synthesis, Structural Characterization, and Redox Transformation.

Abstract

Reductive elimination of Cu(III) intermediates is often proposed as a key step in many copper-catalyzed or -mediated formation of C-C or C-heteroatom bonds. However, there still lacks concrete evidence on this key step, mainly because Cu(III) complexes are usually too unstable to be isolated and structurally characterized. In this work, novel organocopper… (More)
DOI: 10.1021/jacs.7b08803

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