Organochromium Complexes Bearing Noninnocent Diimine Ligands

@article{Kreisel2012OrganochromiumCB,
  title={Organochromium Complexes Bearing Noninnocent Diimine Ligands},
  author={Kevin A. Kreisel and G. Yap and K. Theopold},
  journal={European Journal of Inorganic Chemistry},
  year={2012},
  volume={2012},
  pages={520-529}
}
We have prepared several anionic and neutral organochromium complexes featuring noninnocent α-diimine ligands. All neutral and anionic complexes refrain from insertion of the C=N bonds of the diimine ligand into the chromium–carbon bonds, presumably due to the reduced nature of the diimine ligand. However, insertion can be facilitated by one-electron oxidation. Thus, oxidation of [(HLiPr)CrR(THF)] [HLiPr = Ar–N=C(H)–(H)C=N–Ar in which Ar = 2,6-diisopropylphenyl and R = CH2SiMe3 or CH3] with… Expand
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