Organoantimony(V) cyanoximates: synthesis, spectra and crystal structures.

  title={Organoantimony(V) cyanoximates: synthesis, spectra and crystal structures.},
  author={Konstantin V. Domasevitch and Nikolay Gerasimchuk and Andrew A. Mokhir},
  journal={Inorganic chemistry},
  volume={39 6},
A series of 25 new organoantimony(V) cyanoximates has been synthesized and studied using IR, visible, and NMR spectroscopy and X-ray analysis. Crystal structures were determined for compounds (C6H5)4Sb[ONC(CN)C(O)NH2] (1) and (C6H5)4Sb[ONC(CN)C(O)N(CH3)2] (2). Both complexes crystallized in the monoclinic space group P2(1)/c (Z = 4) with unit cell parameters (A, grad) of a = 14.921(3), b = 10.165(2), c = 17.571(7), beta = 113.26(6) for compound 1, and a = 16.415(4), b = 10.406(3), c = 17.152(3… CONTINUE READING