Order and Mobility of the Fluorescent Probe 1,6-Diphenylhexatriene in a Polyester Liquid Crystal Polymer

Abstract

We have employed time dependent fluorescence polarization to investigate a main chain semiflexible polyester type liquid crystal polymer using the fluorescent probe 1,6-diphenylhexatriene. We have obtained the second rank order parameter and the tumbling reorientational time of the probeas a functionof temperature. Wehave found the polymer disordering to… (More)

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