Optimized Synthesis of Tetrafluoroterephthalic Acid: A Versatile Linking Ligand for the Construction of New Coordination Polymers and Metal-Organic Frameworks

@article{Orthaber2010OptimizedSO,
  title={Optimized Synthesis of Tetrafluoroterephthalic Acid: A Versatile Linking Ligand for the Construction of New Coordination Polymers and Metal-Organic Frameworks},
  author={A. Orthaber and C. Seidel and F. Belaj and J. Albering and R. Pietschnig and U. Ruschewitz},
  journal={Inorganic Chemistry},
  year={2010},
  volume={49},
  pages={9350 - 9357}
}
Pure 2,3,5,6-tetrafluoroterephthalic acid (H2tfBDC) is obtained in high yields (95%) by reacting 1,2,4,5-tetrafluorobenzene with a surplus (>2 equiv) of n-butyllithium in tetrahydrofuran (THF) and subsequent carbonation with CO2 without any extensive purification procedure. A single crystal X-ray structure analysis of H2tfBDC (1) confirms former data obtained for a deuterated sample (P1̅, Z = 1). Recrystallization from water/acetone leads to single crystals of H2tfBDC·2H2O (2, P21/c, Z = 2… Expand
Reproducible Synthesis of a Monofluorinated Trimesate: A Versatile Linking Ligand for the Construction of Lanthanide Coordination Polymers
The synthesis of monofluorinated trimesic acid (H3mfBTC = 2-fluoro-1,3,5-benzene-tricarboxylic acid) described in the literature leads in fact to its monopotassium salt K(H2mfBTC) (1), which wasExpand
Lanthanide coordination polymers with tetrafluoroterephthalate as a bridging ligand: thermal and optical properties.
TLDR
By slow diffusion of triethylamine into a solution of 2,3,5,6-tetrafluoroterephthalic acid and the respective lanthanide salt in EtOH/DMF single crystals of seven nonporous coordination polymers, two-dimensional square grids are obtained and intense emission in the visible region of light for Pr, Sm, and Dy with colors from orange, orange-red, to warm white is revealed. Expand
Metal-organic frameworks based on octafluorobiphenyl-4,4'-dicarboxylate: synthesis, crystal structure, and surface functionality.
TLDR
Low water uptake indicates that both Zn2(oFBPDC)2(dabco)3 and 5 belong to highly hydrophobic solids. Expand
A cooperation molecular recognition study: syntheses and analysis of supramolecular assemblies of tetrafluoroterephthalic acid with some aza compounds
A series of new molecular complexes, both co-crystals and salts, constructed by tetrafluoroterephthalic acid with various aza compound moieties, 3-hydroxypyridine, 2-aminopyrimidine,Expand
Extending the series of p-substituted tetrafluorobenzoic acids: synthesis, properties and structure
Abstract The synthesis of the derivatives of p-aminotetrafluorobenzoic acid, p-H2NC6F4CO2H (2b), by hydrolysis, acylation or interaction with aldehydes was developed giving H2NC6F4CO2K (2a),Expand
Two Anhydrous Salts of Tetrafluoroterephthalic Acid (H2tF-­BDC): K2tF-BDC and Rb2tF-BDC †‡
Two new anhydrous salts of tetrafluoroterephthalic acid (H2tF-BDC), namely K2tF-BDC (1) and Rb2tF-BDC (2), were synthesized and structurally characterized. The crystal structure of 1 (I2/m, Z = 2)Expand
Syntheses, Crystal Structures and Thermal Behavior of Five New Complexes Containing 2, 4, 6‐Trifluorobenzoate as Ligand
Five new complexes containing 2, 4, 6-trifluorobenzoateas ligand have been synthesized and structurally characterized, namely Li(C6F3H2COO)(H2O) (P21, Z = 2, 1),Cs(C6F3H2COO)(C6F3H2COOH) (P21/c, Z =Expand
Crystal Structure of Tris- (2,3,5,6-Tetrafluorobenzoato)Scandium [Sc(C6F4HCO2)3]
The heating of a mixture of as-precipitated scandium hydroxide and tetrafluoroterephthalic acid in methanol is accompanied by acid decarboxylation and the formation of a tris-(2,3,5,6-Expand
Cu(II) coordination polymers constructed by tetrafluoroterephthalic acid and varied imidazole-containing ligands: Syntheses, structures and properties
Abstract Six new copper(II) coordination polymers combining 2,3,5,6-tetrafluoroterephthalatic acid (H2tfBDC) and diverse imidazole-containing ligands, {[Cu(tfBDC)(1,2-bix)2]·2(H2O)}n (1),Expand
[Li2(tF‐BDC)(DMF)2]: A New Alkali Metal Salt of Tetra­fluoroterephthalic Acid (H2tF‐BDC)
The DMF solvate of lithium tetrafluoroterephthalate [Li2(tF-BDC)(DMF)2] (H2tF-BDC = tetrafluoroterephthalic acid) was synthesized and structurally characterized from X-ray single crystal data (Pbcn,Expand
...
1
2
3
...

References

SHOWING 1-7 OF 7 REFERENCES
Growth Des
  • Growth Des
  • 2010
Wuji Huaxue Xuebao ( Chin
  • . J . Inorg . Chem . )
  • 2008
J. Cryst. Growth Des
  • J. Cryst. Growth Des
  • 2007
J. Chem. Soc
  • J. Chem. Soc
  • 1996
Acta Crystallogr., Sect. B: Struct. Sci
  • Acta Crystallogr., Sect. B: Struct. Sci
  • 1980
Acta Crystallogr
  • Acta Crystallogr
  • 1967
Supporting Information Available: Crystallographic data in CIF format. This material is available free of charge via the Internet at http://pubs
  • Supporting Information Available: Crystallographic data in CIF format. This material is available free of charge via the Internet at http://pubs