Operating molecular elevators.

  title={Operating molecular elevators.},
  author={Jovica D Badji{\'c} and C{\'e}lia Machado Ronconi and J. Fraser Stoddart and Vincenzo Balzani and Serena Silvi and Alberto Credi},
  journal={Journal of the American Chemical Society},
  volume={128 5},
Inspired by the concept of multivalency in living systems, two mechanically interlocked molecules have been conceived that incorporate not once or twice but thrice the features of a pH-switchable [2]rotaxane with two orthogonal recognition sites for dibenzo[24]crown-8 (DB24C8), and 2,3-dinaphtho[24]crown-8 (DN24C8)-one a dialkylammonium ion (CH(2)NH(2)(+)CH(2)) and the other a bipyridinium dication (BIPY(2+)). Whereas at low pH, the CH(2)NH(2)(+)CH(2) sites bind the DB24C8/DN24C8 macrocycles… CONTINUE READING