On the volatility of nihonium (Nh, Z = 113)

@article{Aksenov2017OnTV,
  title={On the volatility of nihonium (Nh, Z = 113)},
  author={Nikolay V. Aksenov and Patrick Steinegger and F. S.-H. Abdullin and Yury V. Albin and Gospodin A Bozhikov and V. I. Chepigin and Robert Eichler and Vyacheslav Ya. Lebedev and Alexander Madumarov and O. N. Malyshev and O. V. Petrushkin and Alexandr N. Polyakov and Yu. A. Popov and A. V. Sabel’nikov and R. N. Sagaidak and I. V. Shirokovsky and M. V. Shumeiko and Gennadii Ya. Starodub and Yury Tsyganov and Vladimir Utyonkov and Alexey A. Voinov and Grigory K. Vostokin and A. V. Yeremin and Sergey N. Dmitriev},
  journal={The European Physical Journal A},
  year={2017},
  volume={53},
  pages={1-5}
}
Abstract.Gas-phase chromatography studies of nihonium (Nh, $Z=113$Z=113) were carried out at the one-atom-at-a-time level. For the production of nihonium, the heavy-ion-induced nuclear fusion reaction of 48Ca with 243Am was used. This leads to isotopes 284,285Nh, as the direct descendants of the $\alpha$α-decaying precursors 288,289Mc. Combining the Dubna Gas-Filled Recoil Separator with gas-phase chromatographic separation, the experiment was sensitive to elemental nihonium and its adsorption… 
First Study on Nihonium (Nh, Element 113) Chemistry at TASCA
Nihonium (Nh, element 113) and flerovium (Fl, element 114) are the first superheavy elements in which the 7p shell is occupied. High volatility and inertness were predicted for Fl due to the strong
Properties and Reactivity of Hydroxides of Group 13 Elements In, Tl, and Nh from Molecular and Periodic DFT Calculations.
Adsorption energies, Eads, of gaseous hydroxides of In, Tl, and the superheavy element Nh on surfaces of Teflon and gold are predicted using molecular and periodic relativistic DFT calculations. The
Extraction of thallium and indium isotopes as the homologues of nihonium into the ionic liquids
Extraction of thallium and indium, as the homologues of nihonium, from HCl solutions into hydrophobic ionic liquids was studied. In the presence of NaClO2 as the oxidizing agent, thallium is
Valence states of cyclotron-produced thallium
Unexpected behavior of thallium atoms, produced in a reaction of gold target with accelerated 3He ions, in liquid–liquid extraction with [Cnmim][NTf2] ionic liquids (n = 2, 4, 6–8, 10) was
Co-precipitation behaviour of single atoms of rutherfordium in basic solutions
TLDR
A co-precipitation method with samarium has now been developed that suggests rutherfordium would form hydroxide precipitates—but not ammine ones—if it were possible to perform these experiments on macroscopic quantities.
Online chemical adsorption studies of Hg, Tl, and Pb on SiO2 and Au surfaces in preparation for chemical investigations on Cn, Nh, and Fl at TASCA
Abstract Online gas-solid adsorption studies with single-atom quantities of Hg, Tl, and Pb, the lighter homologs of the superheavy elements (SHE) copernicium (Cn, Z=112), nihonium (Nh, Z=113), and
The periodic table of the elements: the search for transactinides and beyond
The periodic table of Mendeleev, initially proposed on the basis of 66 elements, and containing 82 elements at the time of Moseley (1887–1915), describes nowadays 118 elements. The huge challenge of
Rapid extraction of short-lived isotopes from a buffer gas cell for use in gas-phase chemistry experiments, Part II: On-line studies with short-lived accelerator-produced radionuclides
  • S. Götz, S. Raeder, V. Yakusheva
  • Physics, Environmental Science
    Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms
  • 2021
...
...

References

SHOWING 1-10 OF 36 REFERENCES
Vacuum Chromatography of Tl on SiO2 at the Single-Atom Level
An isothermal vacuum chromatography setup for superheavy element chemistry studies was developed and tested online at the one-atom-at-a-time level. As a model system, the adsorption behavior of
The Inorganic Radiochemistry of Heavy Elements
Volatility of elements and compounds has been occasionally used for radiochemical separations since the studies of Mme. Curie. Steady progress in nuclear sciences and technologies posed new problems
New insights into the 243Am + 48Ca reaction products previously observed in the experiments on elements 113, 115, and 117.
TLDR
Results of a new series of experiments on the study of production cross sections and decay properties of the isotopes of element 115 in the reaction (243)Am+(48)Ca are presented, registering the product of the 2n-evaporation channel, (289)115, for the first time.
Synthesis of elements 115 and 113 in the reaction **243Am+**48Ca
The results of two experiments designed to synthesize element 115 isotopes in the {sup 243}Am+{sup 48}Ca reaction are presented. Two new elements with atomic numbers 113 and 115 were observed for the
The chemistry of superheavy elements. III. Theoretical studies on element 113 compounds
The chemistry of element 113 is investigated by theoretical methods. The results of fully relativistic calculations for (113)H and (113)F are compared with those derived by other techniques to obtain
Thermochemical Data from Gas-Phase Adsorption and Methods of Their Estimation
TLDR
This chapter presents several methods to derive thermodynamic data of the investigated species from these observables, which are not dependent on the experimental parameters and which are therefore intercomparable.
Super-heavy element research.
TLDR
The radioactive properties of the new nuclei, the isotopes of elements 112-118 as well as of their decay products, give evidence of the significant increase of the stability of the heavy nuclei with rise of their neutron number and approaching magic number N = 184.
Chemical characterization of element 112
TLDR
A more reliable chemical characterization of element 112, involving the production of two atoms of 283112 through the alpha decay of the short-lived 287114 and the adsorption of the two atoms on a gold surface, finds that element 112 is very volatile and, unlike radon, reveals a metallic interaction with the gold surface.
...
...