On the upconversion fluorescence in carbon nanodots and graphene quantum dots.

@article{Wen2014OnTU,
  title={On the upconversion fluorescence in carbon nanodots and graphene quantum dots.},
  author={Xiaoming Wen and Pyng Yu and Yon-Rui Toh and Xiaoqian Ma and Jau Tang},
  journal={Chemical communications},
  year={2014},
  volume={50 36},
  pages={
          4703-6
        }
}
Upconversion fluorescence has been frequently cited as an important feature in carbon nanodots (CNDs) and graphene quantum dots (GQDs); and some mechanisms and potential applications have been proposed. Contrary to such a general belief, we demonstrate in this report no observable upconversion fluorescence based on five different synthesized CNDs and GQDs. We confirm that the so-called upconversion fluorescence actually originates from the normal fluorescence excited by the leaking component… 

Figures from this paper

A misunderstanding about upconversion luminescence of carbon quantum dots
During the recent few years, a number of articles based on detecting the upconversion luminescence in graphene quantum dots (GQDs) or carbon quantum dots (CQDs) using spectrofluorimetry with
Carbon Quantum Dots in Nanobiotechnology
TLDR
This chapter is expected to offer beneficial insight into the role of carbon quantum dots in biological applications and encourage more exploration on the topic.
The photoluminescence mechanism in carbon dots (graphene quantum dots, carbon nanodots, and polymer dots): current state and future perspective
At present, the actual mechanism of the photoluminescence (PL) of fluorescent carbon dots (CDs) is still an open debate among researchers. Because of the variety of CDs, it is highly important to
Carbon Quantum Dots: Chemical Synthesis, Properties and Applications
Carbon quantum dots (CQDs) were accidentally discovered in 2004, and since then have attracted considerable research interest due to their unique properties and potential technological applications.
Negative induction effect of graphite N on graphene quantum dots: tunable band gap photoluminescence
We synthesized nitrogen-doped graphene quantum dots (N-GQDs) under a high temperature range of 800–1200 °C and high pressure of 4.0 GPa through a solid-to-solid process. The graphite N in N-GQDs has
Carbon quantum dots and their applications.
TLDR
The progress in the research and development of CQDs is reviewed with an emphasis on their synthesis, functionalization and technical applications along with some discussion on challenges and perspectives in this exciting and promising field.
Glowing graphene quantum dots and carbon dots: properties, syntheses, and biological applications.
TLDR
The properties and synthesis methods of these carbon nanodots are reviewed and emphasis is placed on their biological (both fundamental and theranostic) applications.
Carbon quantum dots: synthesis, properties and applications
Carbon quantum dots (CQDs, C-dots or CDs), which are generally small carbon nanoparticles (less than 10 nm in size) with various unique properties, have found wide use in more and more fields during
Facile synthesis of S, N co-doped carbon dots and investigation of their photoluminescence properties.
TLDR
Interestingly, both down and up conversion fluorescence of the CDs show excitation-independent emission, which is quite different from most of the previously reported CDs, which provides new opportunities for fluorescence sensor designs and light energy conversion applications.
Carbon Quantum Dots: A Component of Efficient Visible Light Photocatalysts
Carbon quantum dots (CQDs) have been developed as a new member of nanocarbons, characterized by the relatively easy preparation from a wide spectrum of carbonaceous precursors through either
...
1
2
3
4
5
...

References

SHOWING 1-10 OF 36 REFERENCES
Facile preparation and upconversion luminescence of graphene quantum dots.
A facile hydrazine hydrate reduction of graphene oxide (GO) with surface-passivated by a polyethylene glycol (PEG) method for the fabrication of graphene quantum dots (GQDs) with frequency
Synthesis and upconversion luminescence of N-doped graphene quantum dots
A hydrothermal approach was developed for the synthesis of N-doped graphene quantum dots (N-GQDs) by cutting N-doped graphene. The N-GQDs obtained have a N/C atomic ratio of ca. 5.6% and diameter of
Upconversion and downconversion fluorescent graphene quantum dots: ultrasonic preparation and photocatalysis.
TLDR
A facile ultrasonic route for the fabrication of graphene quantum dots (GQDs) with upconverted emission is presented, and it is interesting that the photocatalytic rate of the rutile TiO(2)/GQD complex system is ca.
Temperature-Dependent Fluorescence in Carbon Dots
Carbon dots are cost-effective, environmental friendly, and biocompatible nanoparticles with many potential applications in optoelectronics and biophotonics. Their dual fluorescence bands were
Quantum-sized carbon dots for bright and colorful photoluminescence.
We report that nanoscale carbon particles (carbon dots) upon simple surface passivation are strongly photoluminescent in both solution and the solid state. The luminescence emission of the carbon
Focusing on luminescent graphene quantum dots: current status and future perspectives.
TLDR
In this review, the state-of-the-art knowledge of GQDs is presented, with emphasis on the top-down routes which possess the advantages of abundant raw materials, large scale production and simple operation.
Carbon nanodots: synthesis, properties and applications
Carbon nanodots (C-dots) have generated enormous excitement because of their superiority in water solubility, chemical inertness, low toxicity, ease of functionalization and resistance to
Upconversion fluorescent carbon nanodots enriched with nitrogen for light harvesting
Fluorescent nitrogen-enriched carbon nanodots (C-dots) of 1 to 3 nm were obtained through a one-pot reaction between melamine and glycerol. These C-dots show quantum yields up to 22% and a high
Carbon dots for multiphoton bioimaging.
TLDR
The two-photon luminescence microscopy imaging of human breast cancer cells with internalized carbon dots with pulsed laser excitation in the near-infrared is demonstrated.
...
1
2
3
4
...