On the structure of charged interfaces

@article{Bockris1963OnTS,
  title={On the structure of charged interfaces},
  author={JOHN O'M. Bockris and M. A. V. Devanathan and K. M{\"u}ller},
  journal={Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences},
  year={1963},
  volume={274},
  pages={55 - 79}
}
Former models of the electric double layer, and several alternative possibilities, lack consistency with six well-known facts. The paper attempts to adduce models which allow interpretation of these. The potential, not the charge, is the dependent variable in the double layer. The distortion dielectric constant of the water adsorbed on an electrode is six, not n∞2. The constant minimum capacity on the negative branch is interpreted in terms of a model in which Gouy adsorption begins outside the… Expand
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TLDR
By using nanoporous carbon with pores smaller than the size of an ion and a single associated solvent molecule, it is shown that the implicit assumption that double layers are governed only by ion/ electrode charge separation may be short-sighted. Expand
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On the model of the electrical double layer previously proposed by the author, equations are derived for the differential capacity of the metal/electrolyte interface in the presence of organicExpand
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