On the Mechanism of D-amino Acid Oxidase: StructurelReactivity Studies usingp-substituted Phenylglycines

Abstract

o f t h e a H a s H + a n d l e a d s t o a n i n t e r m e d i a t e i n w h i c h t h e s u b s t r a t e a C c a r r i e s a n e g a t i v e c h a r g e . I n t h e " h y d r i d e m e c h a n i s m " a H i s e x p u l s e d f r o m a C H o C o m b i n a t i o n s o f t h e s e m e c h a n i s m s a l s o h a s b e e n p r o p o s e d ( 1 ) . W e h a v e… (More)

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