• DOI:10.1038/s41586-020-2001-x
• Corpus ID: 211195242

On-device lead sequestration for perovskite solar cells

@article{Li2020OndeviceLS,
  title={On-device lead sequestration for perovskite solar cells},
  author={Xun Li and Fei Zhang and Haiying He and Joseph J. Berry and Kai Zhu and Tao Xu},
  journal={Nature},
  year={2020},
  volume={578},
  pages={555-558}
}

• Xun Li, Fei Zhang, +3 authors T. Xu
• Published 1 February 2020
• Materials Science
• Nature

Perovskite solar cells, as an emerging high-efficiency and low-cost photovoltaic technology 1 – 6 , face obstacles on their way towards commercialization. Substantial improvements have been made to device stability 7 – 10 , but potential issues with lead toxicity and leaching from devices remain relatively unexplored 11 – 16 . The potential for lead leakage could be perceived as an environmental and public health risk when using perovskite solar cells in building-integrated photovoltaics 17 – 23 . Here we present a chemical approach for on-device sequestration of more than 96 per cent of lead leakage caused by severe device damage. A coating of lead-absorbing material is applied to the front and back sides of the device stack. On the glass side of the front transparent conducting electrode, we use a transparent lead-absorbing molecular film containing phosphonic acid groups that bind strongly to lead. On the back (metal) electrode side, we place a polymer film blended with lead-chelating agents between the metal electrode and a standard photovoltaic packing film. The lead-absorbing films on both sides swell to absorb the lead, rather than dissolve, when subjected to water soaking, thus retaining structural integrity for easy collection of lead after damage. Using lead-absorbing materials to coat the front and back of perovskite solar cells can prevent lead leaching from damaged devices, without affecting the device performance or long-term operation stability.