Olefin-Directed Palladium-Catalyzed Regio- and Stereoselective Oxidative Arylation of Allenes.

Abstract

An olefin-directed palladium-catalyzed oxidative regio- and stereoselective arylation of allenes to afford 1,3,6-trienes has been established. A number of functionalized allenes, including 2,3- and 3,4-dienoates and 3,4-dienol derivatives, have been investigated and found to undergo the olefin-directed allene arylation. The olefin moiety has been proven to be a crucial element for the arylating transformation.

DOI: 10.1002/anie.201502924

Cite this paper

@article{Zhu2015OlefinDirectedPR, title={Olefin-Directed Palladium-Catalyzed Regio- and Stereoselective Oxidative Arylation of Allenes.}, author={Can Zhu and Bin Yang and Tuo Jiang and Jan-E B{\"a}ckvall}, journal={Angewandte Chemie}, year={2015}, volume={54 31}, pages={9066-9} }