Observation of vibronic emission spectrum of jet-cooled 3,5-difluorobenzyl radical.

Abstract

We applied the technique of corona-excited supersonic expansion using a pinhole-type glass nozzle to observe the vibronic emission spectrum of jet-cooled benzyl-type radicals from the corona discharge of precursor 3,5-difluorotoluene seeded in a large amount of inert helium carrier gas. The vibronically well-resolved emission spectrum was recorded with a… (More)
DOI: 10.1021/jp104161g

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