Observation of hydroxymethyl hydroperoxide in a reaction system containing CH2OO and water vapor through pure rotational spectroscopy.

Abstract

Pure rotational transitions of hydroxymethyl hydroperoxide (HMHP) were observed in the discharged plasma of a CH2I2/O2/water gas mixture, where the water complex with the simplest Criegee intermediate CH2OO has been identified [M. Nakajima and Y. Endo, J. Chem. Phys. 140, 134302 (2014)]. Isotope experiments using heavy water support that the currently… (More)
DOI: 10.1063/1.4933433

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@article{Nakajima2015ObservationOH, title={Observation of hydroxymethyl hydroperoxide in a reaction system containing CH2OO and water vapor through pure rotational spectroscopy.}, author={Masakazu Nakajima and Yasuki Endo}, journal={The Journal of chemical physics}, year={2015}, volume={143 16}, pages={164307} }