Nuclear spin driven quantum tunneling of magnetization in a new lanthanide single-molecule magnet: bis(phthalocyaninato)holmium anion.

@article{Ishikawa2005NuclearSD,
  title={Nuclear spin driven quantum tunneling of magnetization in a new lanthanide single-molecule magnet: bis(phthalocyaninato)holmium anion.},
  author={Naoto Ishikawa and Miki Sugita and Wolfgang Wernsdorfer},
  journal={Journal of the American Chemical Society},
  year={2005},
  volume={127 11},
  pages={
          3650-1
        }
}
The first measurements of magnetization hysteresis loops on a diluted single crystal of [(Pc)2Ho]-.TBA+ (Pc = phthalocyaninato, TBA = tetrabutylammonium) in the subkelvin temperature range are reported. Characteristic staircase-like structure was observed, indicating the occurrence of the quantum tunneling of magnetization (QTM), which is a characteristic feature of SMMs. The quantum process in the new lanthanide SMMs is due to resonant quantum tunneling between entangled states of the… Expand
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