Novel octahedral tungsten sulfidocyanide cluster anion [W6S8(CN)6]6-.

Abstract

Novel tungsten octahedral sulfidocyanide cluster compounds Na6[W6S8(CN)6].18DMSO 1 and K6[W6S8(CN)6] 2 have been synthesized and characterized by X-ray crystallography and NMR spectroscopy. 

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