Nonlinear response of the surface electrostatic potential formed at metal oxide/electrolyte interfaces. A Monte Carlo simulation study.


An analysis of surface potential nonlinearity (psi(0)) at metal oxide/electrolyte interfaces is presented. By using grand canonical Monte Carlo simulations of a simple lattice model of an interface, we show that a correlation exists between ionic strength, as well as surface site densities, and the non-Nernstian response of a metal-oxide electrode. We… (More)
DOI: 10.1016/j.jcis.2009.09.002


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