Non-stationary states in free-radical polymerizations with size-dependent termination. Studies by the group-termination procedure—3. Further consideration of after-and pre-effects and evaluation of absolute coefficients

@inproceedings{Bamford1994NonstationarySI,
  title={Non-stationary states in free-radical polymerizations with size-dependent termination. Studies by the group-termination procedure—3. Further consideration of after-and pre-effects and evaluation of absolute coefficients},
  author={Clement Henry Bamford},
  year={1994}
}
  • Clement Henry Bamford
  • Published 1994
  • Materials Science
  • Abstract In earlier studies of the kinetic quantities in non-stationary stages of non-classical free-radical polymerization a relation between the total pre- and after-effects (ΔMpre, ΔMaf, respectively) and the rate coefficients kpkto was proposed. This arose from the results of numerical computation. Further work shows that the relation is derivable from the basic kinetic equations and is therefore of general validity. We have been able to formulate a new quantity Λ which is a function of the… CONTINUE READING

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