Non perturbative approach for a polar and polarizable linear molecule in an inhomogeneous electric field : Application to molecular beam deviation experiments

Abstract

A non perturbative approach is used to solve the problem of a rigid linear molecule with both a permanent dipole moment and a static dipole polarizability, in a static electric field. Eigenenergies are obtained and compared to perturbative low field and high field approximations. Analytical expressions for the orientation parameters and for the gradient of… (More)

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