Nitroxide spin exchange due to re-encounter collisions in a series of n-alkanes.

@article{Kurban2008NitroxideSE,
  title={Nitroxide spin exchange due to re-encounter collisions in a series of n-alkanes.},
  author={Mark R Kurban and Miroslav Peric and Barney L. Bales},
  journal={The Journal of chemical physics},
  year={2008},
  volume={129 6},
  pages={064501}
}
Bimolecular collisions between perdeuterated 2,2,6,6-tetramethyl-4-oxopiperidine-l-oxyl molecules in three alkanes have been studied by measuring the electron paramagnetic resonance (EPR) spectral changes induced by spin exchange. We define an "encounter" to be a first-time collision followed by a series of re-encounters prior to the diffusing pair's… CONTINUE READING