Nitrosation, Thiols, and Hemoglobin: Energetics and Kinetics


Nitrosothiols are powerful vasodilators. Although the mechanism of their formation near neutral pH is an area of intense research, neither the energetics nor the kinetics of this reaction or of subsequent reactions have been addressed. The following considerations may help to guide experiments. (1) The standard Gibbs energy for the homolysis reaction RSNO… (More)
DOI: 10.1021/ic202561f


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@inproceedings{Koppenol2012NitrosationTA, title={Nitrosation, Thiols, and Hemoglobin: Energetics and Kinetics}, author={Willem H Koppenol}, booktitle={Inorganic chemistry}, year={2012} }