Nickel-thiolate complex catalyst assembled in one step in water for solar H2 production.

@article{Zhang2011NickelthiolateCC,
  title={Nickel-thiolate complex catalyst assembled in one step in water for solar H2 production.},
  author={Wei Zhang and Jindui Hong and Jianwei Zheng and Zhiyan Huang and Jianrong Steve Zhou and Rong Xu},
  journal={Journal of the American Chemical Society},
  year={2011},
  volume={133 51},
  pages={20680-3}
}
We report the use of a simple complex assembled from Ni(II) salt and 2-mecaptoethanol in one step in water as the efficient catalyst in a molecular hydrogen system which can be sensitized by a low-cost xanthene dye, Erythrosin B. An excellent quantum efficiency of 24.5% is attained at 460 nm. This simple system is expected to contribute toward the development of economical and environmentally benign solar hydrogen production systems. 
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