Nickel-catalyzed amination of aryl chlorides with ammonia or ammonium salts.


The nickel-catalyzed amination of aryl chlorides to form primary arylamines occurs with ammonia or ammonium sulfate and a well-defined single-component nickel(0) precatalyst containing a Josiphos ligand and an η(2)-bound benzonitrile ligand. This system also catalyzes the coupling of aryl chlorides with gaseous amines in the form of their hydrochloride… (More)
DOI: 10.1002/anie.201500404


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@article{Green2015NickelcatalyzedAO, title={Nickel-catalyzed amination of aryl chlorides with ammonia or ammonium salts.}, author={Rebecca A. Green and John F Hartwig}, journal={Angewandte Chemie}, year={2015}, volume={54 12}, pages={3768-72} }