Nickel-catalysed addition of organoboronates to 1,3-dienes.


Aryl- and alkenylboronates were found to add to 1,3-dienes in the presence of a catalytic amount of bis(1,5-cyclooctadiene)nickel, where a proton source in combination with a solvent considerably controls the regioselectivity. 


Cite this paper

@article{Shirakawa2002NickelcatalysedAO, title={Nickel-catalysed addition of organoboronates to 1,3-dienes.}, author={Eiji Shirakawa and Go Takahashi and Teruhisa Tsuchimoto and Yusuke Kawakami}, journal={Chemical communications}, year={2002}, volume={19}, pages={2210-1} }