Ni(II) complexes featuring non-metallated pincer-type ligands.

@article{Pandarus2008NiIICF,
  title={Ni(II) complexes featuring non-metallated pincer-type ligands.},
  author={Valerica Pandarus and A. Castonguay and D. Zargarian},
  journal={Dalton transactions},
  year={2008},
  volume={35},
  pages={
          4756-61
        }
}
  • Valerica Pandarus, A. Castonguay, D. Zargarian
  • Published 2008
  • Chemistry, Medicine
  • Dalton transactions
  • Attempts to prepare pincer-type Ni complexes from the ligands (i-Pr(2)POCH(2))(2)CH(2) and (pz*CH(2))(2)CH(2) (pz* = 3,5-dimethylpyrazol-1-yl) gave instead the complexes cis-{kappa(P),kappa(P')-(i-Pr(2)POCH(2))(2)CH(2)}NiCl(2) and {kappa(N),kappa(N')-(pz*CH(2))(2)CH(2)}NiBr(2). X-Ray diffraction studies confirmed that these potentially pincer-type ligands have not undergone metallation, serving instead as chelating ligands in essentially square-planar or tetrahedral complexes. Heating of these… CONTINUE READING
    26 Citations

    Figures, Tables, and Topics from this paper

    Explore Further: Topics Discussed in This Paper

    References

    SHOWING 1-10 OF 63 REFERENCES
    New pincer-type diphosphinito (POCOP) complexes of NiII and NiIII.
    • 88
    • PDF