New synthetic routes to cationic rhenium tricarbonyl bipyridine complexes with labile ligands.

Abstract

Triflate abstraction from the complex [Re(OTf)(CO)(3)(bipy)] (1) using the salt NaBAr'(4) (Ar' = 3,5-bis(trifluoromethyl)phenyl) in dichloromethane solution in the presence of L = PPh(3), NCMe, NCPh, imines, ketones, Et(2)O, THF, MeOH, and MeI affords cationic complexes [Re(L)(CO)(3)(bipy)](+) as their BAr'(4)(-) salts. The new complexes have been… (More)

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Cite this paper

@article{Hevia2002NewSR, title={New synthetic routes to cationic rhenium tricarbonyl bipyridine complexes with labile ligands.}, author={Eva Hevia and Julio P{\'e}rez and V{\'i}ctor Riera and Daniel Miguel and Scott Kassel and Arnold L. Rheingold}, journal={Inorganic chemistry}, year={2002}, volume={41 18}, pages={4673-9} }