New riches in carbaporphyrin chemistry: silver and gold organometallic complexes of benzocarbaporphyrins.

@article{Lash2004NewRI,
  title={New riches in carbaporphyrin chemistry: silver and gold organometallic complexes of benzocarbaporphyrins.},
  author={T. D. Lash and D. A. Colby and L. F. Szczepura},
  journal={Inorganic chemistry},
  year={2004},
  volume={43 17},
  pages={
          5258-67
        }
}
The NH-N-NH-N core of the porphyrin system represents one of the best studied and most versatile platforms for coordination chemistry. However, the replacement of one or more of the interior nitrogens with carbon atoms would be expected to diminish the ability of these systems to form metallo derivatives considerably. Despite this expectation, carbaporphyrinoid systems have been shown to form stable organometallic derivatives. Although azuliporphyrins and benziporphyrins act as dianionic… Expand
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