New perspective for natural products synthesis: concise synthesis of (+)-sch 642305 by chiral auxiliary multiuse methodology.

@article{Fujioka2007NewPF,
  title={New perspective for natural products synthesis: concise synthesis of (+)-sch 642305 by chiral auxiliary multiuse methodology.},
  author={H. Fujioka and Yusuke Ohba and Kenji Nakahara and Mayuko Takatsuji and Kenichi Murai and Motoki Ito and Y. Kita},
  journal={Organic letters},
  year={2007},
  volume={9 26},
  pages={
          5605-8
        }
}
The synthesis of (+)-Sch 642305 is an example of chiral auxiliary multiuse methodology, which shows a new perspective for the synthesis of compounds with multiple asymmetric centers. Thus, (+)-Sch 642305 was concisely synthesized from the known compound. Every reaction is stereoselective, and the chiral nonracemic hydrobenzoin worked as chiral auxiliary for desymmetrization of diene, as a template for attaining regio- and stereoselective reactions, as an oxygen source at the C4-position, and as… Expand
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