New insights into solvolysis and reorganization energy from gas-phase, electrochemical, and theoretical studies of oxo-Tp*Mo(V) molecules.

Abstract

Molecules of the general form Tp*MoO(OR)(2) [where Tp* = hydrotris(3,5-dimethyl-1-pyrazolyl)borate and (OR)(2) = (OMe)(2), (OEt)(2), and (O(n)Pr)(2) for alkoxide ligands and (OR)(2) = O(CH(2))(3)O, O(CH(2))(4)O, and O[CH(CH(3))CH(2)CH(CH(3))]O for diolato ligands] were studied using gas-phase photoelectron spectroscopy, cyclic voltammetry, and density… (More)
DOI: 10.1021/ic9011058

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