New dinuclear cobalt(II) and zinc(II) complexes of a carboxylate-rich dinucleating ligand: synthesis, structure, spectroscopic characterization, and their interactions with sugars.

Abstract

Sugar-metal ion interactions in aqueous medium are involved in many biochemical processes such as the transport and storage of metals, the function and regulation of sugar-metabolizing metalloenzymes, the mechanism of action of metal-containing pharmaceuticals, and toxic metal metabolism. To understand such interactions we synthesized and fully… (More)
DOI: 10.1021/ic3004432

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