Neutral and acidic products derived from hydroxyl radical-induced oxidation of arabinotriose assessed by electrospray ionisation mass spectrometry.

@article{Moreira2014NeutralAA,
  title={Neutral and acidic products derived from hydroxyl radical-induced oxidation of arabinotriose assessed by electrospray ionisation mass spectrometry.},
  author={A. Moreira and E. da Costa and D. Evtuguin and M. Coimbra and F. Nunes and M. Domingues},
  journal={Journal of mass spectrometry : JMS},
  year={2014},
  volume={49 4},
  pages={
          280-90
        }
}
The oxidation of α-(1 → 5)-L-arabinotriose (Ara3), an oligosaccharide structurally related to side chains of coffee arabinogalactans, was studied in reaction with hydroxyl radicals generated under conditions of Fenton reaction (Fe(2+)/H2O2). The acidic and neutral oxidation products were separated by ligand exchange/size-exclusion chromatography, subsequently identified by electrospray ionisation mass spectrometry (ESI-MS) and structurally characterised by tandem MS (ESI-MS/MS). In acidic… Expand
Evaluation of the photooxidation of galactosyl- and lactosylceramide by electrospray ionization mass spectrometry.

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