Nanospheric [M20(OH)12(maleate)12(Me2NH)12]4+ clusters (M = Co, Ni) with O(h) symmetry.

@article{Gui2012NanosphericC,
  title={Nanospheric [M20(OH)12(maleate)12(Me2NH)12]4+ clusters (M = Co, Ni) with O(h) symmetry.},
  author={L. Gui and Xiuran Wang and Qing-ling Ni and Miao Wang and Fupei Liang and Huahong Zou},
  journal={Journal of the American Chemical Society},
  year={2012},
  volume={134 2},
  pages={
          852-4
        }
}
Nanospheric hydroxo-bridged clusters of [M(20)(OH)(12)(maleate)(12)(Me(2)NH)(12)](BF(4))(3)(OH)·nH(2)O (M = Co (1), Ni (2)) with O(h) symmetry were afforded under hydrothermal condition with Co(BF(4))(2)·6H(2)O/Ni(BF(4))(2)·6H(2)O and fumaric acid in a DMF/EtOH mixed solvent. They are characterized by elemental analysis, IR, and X-ray diffraction. X-ray single crystal diffraction analyses show that these two complexes are isostructural containing an ideally cubic M(8) core in that each two M… Expand
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