NO/H2S "Crosstalk" Reactions. The Role of Thionitrites (SNO-) and Perthionitrites (SSNO-).

  title={NO/H2S "Crosstalk" Reactions. The Role of Thionitrites (SNO-) and Perthionitrites (SSNO-).},
  author={J. P. Marcolongo and M. Ven{\^a}ncio and W. Rocha and F. Doctorovich and J. A. Olabe},
  journal={Inorganic chemistry},
  • J. P. Marcolongo, M. Venâncio, +2 authors J. A. Olabe
  • Published 2019
  • Chemistry, Medicine
  • Inorganic chemistry
  • The redox chemistry of H2S with NO and other oxidants containing the NO group is discussed on a mechanistic basis because of the expanding interest in their biological relevance, with an eye open to the chemical differences of H2S and thiols RSH. We focus on the properties of two "crosstalk" intermediates, SNO- (thionitrite) and SSNO- (perthionitrite, nitrosodisulfide) based in the largely controversial status on their identity and chemistry in aqueous/nonaqueous media, en route to the final… CONTINUE READING
    7 Citations
    Spectroscopic identification of the •SSNO isomers.
    The Role of Host-Generated H2S in Microbial Pathogenesis: New Perspectives on Tuberculosis
    • PDF
    The Solution Chemistry of Nitric Oxide and Other Reactive Nitrogen Species.