• DOI:10.1021/acs.inorgchem.9b01978
Corpus ID: 207934762

NO/H2S "Crosstalk" Reactions. The Role of Thionitrites (SNO-) and Perthionitrites (SSNO-).

@article{Marcolongo2019NOH2SR,
  title={NO/H2S "Crosstalk" Reactions. The Role of Thionitrites (SNO-) and Perthionitrites (SSNO-).},
  author={J. P. Marcolongo and M. Ven{\^a}ncio and W. Rocha and F. Doctorovich and J. A. Olabe},
  journal={Inorganic chemistry},
  year={2019}
}

J. P. Marcolongo, M. Venâncio, +2 authors J. A. Olabe

Published 2019

Chemistry, Medicine

Inorganic chemistry

The redox chemistry of H2S with NO and other oxidants containing the NO group is discussed on a mechanistic basis because of the expanding interest in their biological relevance, with an eye open to the chemical differences of H2S and thiols RSH. We focus on the properties of two "crosstalk" intermediates, SNO- (thionitrite) and SSNO- (perthionitrite, nitrosodisulfide) based in the largely controversial status on their identity and chemistry in aqueous/nonaqueous media, en route to the final… CONTINUE READING

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