NMR, IR/Raman, and structural properties in HNO and RNO (R = alkyl and aryl) metalloporphyrins with implication for the HNO-myoglobin complex.


Structural and functional details of heme protein complexes with HNO and the isoelectronic RNO (R = alkyl and aryl) molecules (metabolic intermediates) are largely unknown. We report a quantum chemical investigation of three characteristic spectroscopic properties, (1)H and (15)N NMR chemical shifts and NO vibrational frequencies in synthetic HNO and RNO… (More)
DOI: 10.1021/ja907342s

7 Figures and Tables


  • Presentations referencing similar topics