N2O decomposition over Fe/ZSM-5: reversible generation of highly active cationic Fe species.

Abstract

Fe-oxide species in Fe/ZSM-5 (prepared by chemical vapor deposition of FeCl3)--active in N2O decomposition--react with zeolite protons during high temperature calcination to give highly active cationic Fe species, this transformation being reversible upon exposure to water vapor at lower temperature. 

Topics

Cite this paper

@article{Zhu2002N2ODO, title={N2O decomposition over Fe/ZSM-5: reversible generation of highly active cationic Fe species.}, author={Q. Zhu and Emiel J M Hensen and Barbara Louise Mojet and J H M C van Wolput and Rutger A. van Santen}, journal={Chemical communications}, year={2002}, volume={11}, pages={1232-3} }