N-Heterocyclic Carbene Catalyzed Stereoselective Glycosylation of 2-Nitrogalactals.


An efficient N-heterocyclic carbene catalyzed glycosylation of 2-nitrogalactals with alcohols and phenol has been developed for the first time. A wide variety of 1,2-cis-2-nitroglycosides can be obtained with good to excellent yields and high to excellent α-selectivities. 
DOI: 10.1021/acs.orglett.7b02543


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