N,N'-ditosylhydrazine: a convenient reagent for facile synthesis of diazoacetates.

@article{Toma2007NNditosylhydrazineAC,
  title={N,N'-ditosylhydrazine: a convenient reagent for facile synthesis of diazoacetates.},
  author={Tatsuya Toma and Jun Shimokawa and Tohru Fukuyama},
  journal={Organic letters},
  year={2007},
  volume={9 16},
  pages={3195-7}
}
A novel entry to the synthesis of diazoacetates is disclosed. A variety of diazoacetates were synthesized from the corresponding bromoacetates by treatment with N,N'-ditosylhydrazine in moderate to high yields. Ease of operation with the stable crystalline reagent as well as a short reaction time offer a useful alternative to the conventional methods. 

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