Multiple phase inversion of emulsions stabilized by in situ surface activation of CaCO3 nanoparticles via adsorption of fatty acids.

@article{Cui2012MultiplePI,
  title={Multiple phase inversion of emulsions stabilized by in situ surface activation of CaCO3 nanoparticles via adsorption of fatty acids.},
  author={Z-G Cui and C-F Cui and Yudan Zhu and Bernard P Binks},
  journal={Langmuir : the ACS journal of surfaces and colloids},
  year={2012},
  volume={28 1},
  pages={314-20}
}
The in situ surface activation of raw CaCO(3) nanoparticles by interaction with a series of sodium carboxylates of chain length between 6 and 12 as well as sodium 2-ethylhexylsulfosuccinate (AOT) was studied, and the impact of this on the stabilization and phase inversion of toluene-water emulsions was assessed. By using complementary experiments including measurement of particle zeta potentials, adsorption isotherms of amphiphile, and relevant contact angles, the mechanism of this activation… CONTINUE READING
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