Multiple-electron transfer in a single step. Design and synthesis of highly charged cation-radical salts.

Abstract

[structure: see text]. Macromolecules 1c and 2c bearing multiple redox-active sites are synthesized by an efficient palladium-catalyzed coupling of 2,5-dimethoxytolylmagnesium bromide with readily available hexakis(4-bromophenyl)benzene and tetrakis(4-bromophenyl)methane. These macromolecular electron donors undergo reversible oxidation at a constant… (More)

Topics

Cite this paper

@article{Rathore2001MultipleelectronTI, title={Multiple-electron transfer in a single step. Design and synthesis of highly charged cation-radical salts.}, author={Rajendra Rathore and Claire L. Burns and Mihaela I Deselnicu}, journal={Organic letters}, year={2001}, volume={3 18}, pages={2887-90} }