Molecular hydrogen occupancy in binary THF-H2 clathrate hydrates by high resolution neutron diffraction.

@article{Hester2006MolecularHO,
  title={Molecular hydrogen occupancy in binary THF-H2 clathrate hydrates by high resolution neutron diffraction.},
  author={Keith C. Hester and Timothy A Strobel and E. Dendy Sloan and Carolyn A Koh and A. S. M. Anwarul Huq and Arthur J. Schultz},
  journal={The journal of physical chemistry. B},
  year={2006},
  volume={110 29},
  pages={14024-7}
}
We have determined the time-space average filling of hydrogen molecules in a binary tetrahydrofuran (THF)-d(8) + D(2) sII clathrate hydrate using high resolution neutron diffraction. The filling of hydrogen in the lattice of a THF-d(8) clathrate hydrate occurred upon pressurization. The hydrogen molecules were localized in the small dodecahedral cavities at… CONTINUE READING