Molecular cavity optomechanics as a theory of plasmon-enhanced Raman scattering.


The exceptional enhancement of Raman scattering by localized plasmonic resonances in the near field of metallic nanoparticles, surfaces or tips (SERS, TERS) has enabled spectroscopic fingerprinting down to the single molecule level. The conventional explanation attributes the enhancement to the subwavelength confinement of the electromagnetic field near… (More)
DOI: 10.1038/nnano.2015.264


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