• DOI:10.1021/MA00128A003
Corpus ID: 96263484

Molecular and Structural Characterization of Polydisperse Polymers and Copolymers by Combining MALDI-TOF Mass Spectrometry with GPC Fractionation

@article{Montaudo1995MolecularAS,
  title={Molecular and Structural Characterization of Polydisperse Polymers and Copolymers by Combining MALDI-TOF Mass Spectrometry with GPC Fractionation},
  author={G. Montaudo and D. Garozzo and M. Montaudo and C. Puglisi and F. Samperi},
  journal={Macromolecules},
  year={1995},
  volume={28},
  pages={7983-7989}
}

G. Montaudo, D. Garozzo, +2 authors F. Samperi

Published 1995

Chemistry

Macromolecules

Matrix assisted laser desorption ionization-time of flight mass spectrometry (MALDI-TOF MS) allows detection of large molecules such as those present in synthetic and natural macromolecules. Until recently, it was reported that MALDI-TOF measurements can provide correct molecular weight (MW) averages only for samples with a narrow MW distribution (M w /M n ≤ 1.20). We have now developed a methodology for polydisperse samples. We recorded the GPC trace of two polydisperse polymeric samples… CONTINUE READING

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