Modeling the free energy surfaces of electron transfer in condensed phases

@inproceedings{Matyushov2000ModelingTF,
  title={Modeling the free energy surfaces of electron transfer in condensed phases},
  author={Dmitry V Matyushov and Gregory A. Voth},
  year={2000}
}
We develop a three-parameter model of electron transfer (ET) in condensed phases based on the Hamiltonian of a two-state solute linearly coupled to a harmonic, classical solvent mode with different force constants in the initial and final states (a classical limit of the quantum Kubo–Toyozawa model). The exact analytical solution for the ET free energy surfaces demonstrates the following features: (i) the range of ET reaction coordinates is limited by a one-sided fluctuation band, (ii) the ET… CONTINUE READING

Citations

Publications citing this paper.
SHOWING 1-10 OF 14 CITATIONS

Solvent Electrostatic Response: From Simple Solutes to Proteins

VIEW 48 EXCERPTS
CITES BACKGROUND & METHODS
HIGHLY INFLUENCED

Protein electron transfer: is biology (thermo)dynamic?

  • Journal of physics. Condensed matter : an Institute of Physics journal
  • 2015
VIEW 2 EXCERPTS
CITES BACKGROUND

Reaction dynamics at liquid interfaces.

  • Annual review of physical chemistry
  • 2015
VIEW 2 EXCERPTS
CITES BACKGROUND