Model dialkyl peroxides of the fenton mechanistic probe 2-methyl-1-phenyl-2-propyl hydroperoxide (MPPH): kinetic probes for dissociative electron transfer.


Two dialkyl peroxides, devised as kinetic probes for the heterogeneous electron transfer (ET), are studied using heterogeneous and homogeneous electrochemical techniques. The peroxides react by concerted dissociative ET reduction of the O-O bond. Under heterogeneous conditions, the only products isolated are the corresponding alcohols from a two-electron… (More)


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