Mo and W bis-MGD enzymes: nitrate reductases and formate dehydrogenases

@article{Moura2004MoAW,
  title={Mo and W bis-MGD enzymes: nitrate reductases and formate dehydrogenases},
  author={Jos{\'e} J. G. Moura and C. D. Brondino and Jos{\'e} Trinc{\~a}o and Maria Jo{\~a}o Rom{\~a}o},
  journal={JBIC Journal of Biological Inorganic Chemistry},
  year={2004},
  volume={9},
  pages={791-799}
}
Molybdenum and tungsten are second- and third-row transition elements, respectively, which are found in a mononuclear form in the active site of a diverse group of enzymes that generally catalyze oxygen atom transfer reactions. Mononuclear Mo-containing enzymes have been classified into three families: xanthine oxidase, DMSO reductase, and sulfite oxidase. The proteins of the DMSO reductase family present the widest diversity of properties among its members and our knowledge about this family… CONTINUE READING
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